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Around S = 1.4, the GS flux starts to increase more slowly while the GPX flux still increases at roughly the same rate as S increases, so the GSH curve starts to level off and reaches a maximum at S = 1.8

[PubMed 9194988] 2086

Finally, because glutathione is a potent antioxidant, it neutralizes the free radicals that trigger melanin production in the first place

GSH conjugation allows fast release of AUY922 to the tumor site and cellular uptake through transferrin receptor [195]

Both of these isozymes have been putatively linked to assist the oxidative protein folding process in the ER using hydrogen peroxide and GSH as substrates [1, 8]