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The formation of Glc-6-P from free glucose and inorganic phosphate is energetically unfavorable, so that a molecule of ATP must be expended or invested in the phosphorylation reaction

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4.2 Mn routes into the brain Mn can enter the brain via three routes: the blood-brain barrier (BBB), the blood-cerebrospinal fluid barrier, and the olfactory nerve terminals (Figure 2)