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Divergence from the optimal dihedral also results in increased overlap between the sulfur p -orbital lone pair and the adjacent carbonyl non-bonding * orbital, decreasing the likelihood of homolytic disulfide bond cleavage

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(Doctor language, I know!) What that means is that when there is tissue injury (such as during surgery) the body naturally produces peptides to direct the wound healing process

This problem may worsen in the near future because of limited available S in the environment, due to decreased pollution-driven SO 2 emissions and lower utilization of S-containing fertilisers (such as superphosphate)

Liver Int 43 , 20782095 (2023)