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Theres no evidence from human clinical trials that NAC causes cancer

doi:10.1016/j.femsyr.2005.06.001 Elskens MT, Jaspers CJ, Penninckx MJ (1991) Glutathione as an endogenous sulphur source in the yeast Saccharomyces cerevisiae

In the resting state, MPO contains iron in oxidation state 3 + (MPO-Fe(III)), and in the course of the peroxidase cycle, H 2 O 2 interacts with the Fe(III) heme center, supported by hydrogen bonds with the H 2 O molecule and histidine95