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In order to demonstrate potential for biological applications, along with compatibility with longer peptides, an i,i + 4 stapled analog of the 11-mer linear peptide ligand that binds the co-activator binding site of estrogen receptor was synthesized

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Supporting the hypothesis that the salvage pathway has a major function in regulating intracellular BH4 levels, the same investigators observed that despite administering the unnatural diastereomer 6 S -BH4 to mice, a large proportion of the deposited BH4 (more than 95% was in the liver) was in the form of the 6 R -diastereomer [81,33]

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