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doi: 10.3389/fbioe.2024.1417600 Received 12 May 2024 Accepted 19 August 2024 Published 26 August 2024 Volume 12 - 2024 Edited by Pablo Taboada, University of Santiago de Compostela, Spain Reviewed by Peikai Chen, The University of Hong Kong, China Caihong Zhu, Soochow University Medical College, China Updates Copyright 2024 Sono, Shima, Shimizu, Murata, Matsuda and Otsuki

Zinc has the capacity to preserve the integrity of the bloodbrain barrier (BBB), a highly specialized semipermeable and selective vascular system within the central nervous system of most vertebrates (Noseworthy and Bray, 2000[327])

We report here the synthesis of three new disulfide-linked dinitroxides, whose EPR spectra change dramatically upon reaction with glutathione, and the characterization of the kinetics of their reaction with glutathione