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This is also an illustration of the fact that, in addition to the occurrence of merely metabolic control factors, such as the lack of adequate levels of cofactors or precursors for biosynthesis, transport limitations can occur during biotransformations (see previous section)

The results of the study showed that intravenous magnesium could relieve acute attacks between 15 min and 24 h after infusion, and oral magnesium significantly reduced the frequency and intensity of migraine attacks (187)

Indeed, 4-en-VPA is transformed through -oxidation to reactive intermediates such as 2-propyl-2, 4-pentadienoic acid (2, 4-dien-VPA) that are capable of depleting mitochondrial GSH, as suggested by rat studies [60]

Therefore, melatonin and several melatonin analogues (e.g., ramelteon, agomelatine, and tasimelteon) are currently used to treat sleep disorders, prevent desynchronosis (jet lag), as an antioxidant, and in other conditions [76]

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