glutathione perivenous hepatocytes Spatial heterogeneity in the mammalian liver Differential gene expression in periportal

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The oxidized PUFA tail then gets cleaved by phospholipases, causing accumulation of lysophospholipids (lysoPLs)

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Finally, in different mouse models of FRDA, a chronological analysis of phenotypic appearance showed that the FeS cluster deficit appears very early in the course of the disease, followed by the cardiac symptoms, oxidative stress and only afterward iron deposition, thus pointing to iron accumulation as a late, secondary effect of the Fe-S cluster defect (Puccio et al., 2001

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